4.7 Article

Strong Hydrogen Binding within a 3D Microporous Metal-Organic Framework

Journal

INORGANIC CHEMISTRY
Volume 48, Issue 18, Pages 8656-8658

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic900968d

Keywords

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Funding

  1. NSFC [20625103, 20831005, 20821001]
  2. 973 Program of China [2007CB815305]

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A 3D microporous cadmium(II) metal-organic framework based on 1H-tetrazole exhibits strong hydrogen binding with an initial enthalpy of adsorption of 13.3 kJ/mol, due to the smaller pore sizes and the high hydrogen binding affinity of the tetrazolyl-ring-decorated inner surface of the pores.

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