Journal
INORGANIC CHEMISTRY
Volume 48, Issue 13, Pages 5617-5619Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900879d
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Funding
- Korea Science and Engineering Foundation (KOSEF) [R01-2007-000-10240-0]
- National Research Foundation of Korea [R01-2007-000-10240-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Cyanide-bridged M-V-Mn-III (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)(8)](3-) precursors and Wit Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.
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