Journal
INORGANIC CHEMISTRY
Volume 48, Issue 12, Pages 5398-5402Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900475q
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Funding
- U.S. Department of Energy [DEFC36-07GO17033]
- National Science Foundation [CHE-0449634]
- Argonne National Laboratory
- Institutional Research Program [KK-0904-A0]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0910761] Funding Source: National Science Foundation
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Three isomorphous porous metal-organic frameworks (MOFs; PCN-9 (Co/Fe/Mn)) with entatic metal centers have been constructed on the basis of the trigonal planar H(3)TATB ligand and a novel square-planar secondary building unit. N-2 adsorption isotherms at 77 K confirmed the permanent porosities of the three porous MOFs. Variable-temperature adsorption measurements of H-2 revealed that the H-2 affinities of the three porous MOFs are related to the nature of entatic metal centers, which reversely affect their H-2 uptake capacities.
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