Journal
INORGANIC CHEMISTRY
Volume 48, Issue 13, Pages 5587-5589Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic9003017
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Funding
- Packard Foundation
- University of Erlangen-Nurnberg
- DFG (SFB 583)
- Alexander von Humboldt Foundation
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Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene) to the bis(imino)pyridine iron bis(dinitrogen) complex, ((PDI)-P-iPr)Fe(N-2)(2) ((PDI)-P-iPr = 2,6-(2,6-(Pr2C6H3N)-Pr-i=CMe)(2)C5H3N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [((PDI)-P-iPr)FeNH].
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