Journal
INORGANIC CHEMISTRY
Volume 48, Issue 14, Pages 6344-6346Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900808f
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Funding
- National Natural Science Foundation of China [20490210]
- MOST of China [2006CB-601103]
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An imidosamarium(III) cubane has been prepared from the reductive cleavage of azobenzene by a divalent samarium bis (amidinate) complex, indicating that the spectratoe bis(amidinate) and the resulting imido ligands help to stabilize the cubane framework. The cubane-type imido cluster is a novel unit in lanthanide chemistry.
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