Journal
INORGANIC CHEMISTRY
Volume 48, Issue 4, Pages 1263-1265Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic8019952
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- National Science Council of the Republic of China [NSC 95-2113-M-153-001-MY3]
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An unusual iridium complex, [(dfpbo)(2)Ir](2) [dfpbo = 2-(3,5-difluorophenyl)benzoxazolato-N,C-2'], which is the first dimeric iridium complex composed of two bis-cyclometalated Ir-II structures connected by an unsupported Ir-II-Ir-II bond, has been synthesized and fully characterized. Under mild conditions of neutral pH at room temperature, this complex dissociated spontaneously to form the stable radical [Ir(dfpbo)(2)](center dot),
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