Journal
INORGANIC CHEMISTRY
Volume 48, Issue 13, Pages 6004-6010Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900322d
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Funding
- NCI NIH HHS [R01 CA119371-01, R01 CA119371, 1R01-CA119371-01] Funding Source: Medline
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The structures of two newly synthesized endohedral fullerenes, Tm C-3v-C-94 and Ca C-3v-C-94, have been determined by single crystal -ray diffraction on samples cocrystallized with N-II(octaethylporphyrin). Both compounds exhibit the same cage geometry and conform to the isolated pentagon rule (IPR). The metalions within these rather large cages are localized near one end and along the C-3 axis. While the calcium ion is situated over a C-C bond at a 6:6 ring juncton, the thulium ion is positioned above a six-membered ring of the fullerene.
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