Journal
INORGANIC CHEMISTRY
Volume 48, Issue 2, Pages 417-419Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic801906e
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Funding
- Korean Government (MOEHRD) [KRF-2006-331-C00157]
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A surprisingly small number of topologies are known in metal-organic frameworks (MOFs) that possess Zn-4(O)(O2C)(6) building units. One of such MOFs having a simple, nonlinear dicarboxylate ligand, 5-methylisophthalate (mip), is targeted and successfully synthesized. The framework, [Zn-4(O)(mip)(3)], is based on a nonuniform, uninodal six-connected net and is featured by complicated meshlike pores with narrow passages. Gas sorption studies reveal the potentials as a prototype from which new MOFs having interesting properties can be derived.
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