4.7 Article

Metal-Organic Framework Assembled from T-Shaped and Octahedral Nodes: A Mixed-Linker Strategy To Create a Rare Anatase TiO2 Topology

Journal

INORGANIC CHEMISTRY
Volume 48, Issue 19, Pages 9060-9062

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic9009916

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Funding

  1. Nebraska EPSCoR
  2. Nebraska Center for Energy Sciences Research
  3. Nebraska Center for Materials and Nanoscience
  4. Research Council of the University of Nebraska-Lincoln

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A novel porphyrin paddlewheel framework (PPF-25), assembled from a zinc paddlewheel cluster and mixed linkers (4,4'-bipyridyl; zinc 5,15-di(4-carboxyphenyl)-10,20-diphenylporphyrin), has been synthesized and structurally characterized. T-shaped organometallic nodes are generated, and the resulting structure is closely related to anatase, a polymorph of TiO2,

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