4.7 Article

A Large-Surface-Area Boracite-Network-Topology Porous MOF Constructed from a Conjugated Ligand Exhibiting a High Hydrogen Uptake Capacity

Journal

INORGANIC CHEMISTRY
Volume 48, Issue 16, Pages 7519-7521

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic901073w

Keywords

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Funding

  1. U.S. DOE [DE-FC36-07GO17033]
  2. National Science Foundation [CHE-0449634]
  3. Argonne National Laboratory
  4. Institutional Research Program
  5. National Science Foundation/DOE [CHE-0535644]
  6. U.S. DOE, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
  7. Division Of Chemistry
  8. Direct For Mathematical & Physical Scien [0822838] Funding Source: National Science Foundation

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A new porous metal-organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m(2)/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

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