Journal
INORGANIC CHEMISTRY
Volume 48, Issue 23, Pages 10883-10885Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic9016454
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Funding
- Swedish Research Council
- Swedish Energy Agency
- Knut and Alice Wallenberg Foundation
- Klaus Tschira Foundation
- EU
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Biphenyl-2,2'-dithiolate (bpdt) bridged Fe-2(bpdt)(CO)(6) (1) undergoes two sequential electrochemically quasi-reversible reductions. The one-electron reduction product 1(-) is unusually stable against irreversible structural changes and could be characterized by IR and EPR spectroscopy supported by computational methods. Reduction to the (I,0) state does not trigger bridging coordination of CO but partial deligation of the dithiolate in 1(-) that ultimately forms a diamagnetic dimerization product.
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