Journal
INORGANIC CHEMISTRY
Volume 48, Issue 6, Pages 2358-2360Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900017s
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [18GS0207, 18064009]
- Grants-in-Aid for Scientific Research [18064009] Funding Source: KAKEN
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A dithiolate-bridged dinuclear Fe-Ni complex, which has the desired fac-(CN)(2)(CO) ligand set at iron, has been synthesized. Its CN/CO bands in the IR spectrum reproduce those of the Ni-A, Ni-B, and Ni-SU states, which indicate that these octahedral Fell centers have similar electronic properties. This result verifies the assignment of a (CN)(2)(CO)Fe-II moiety in the active site of [NiFe] hydrogenase.
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