Journal
INORGANIC CHEMISTRY
Volume 48, Issue 4, Pages 1266-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic8021672
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Funding
- NSFC [50372069, 20671090]
- CAS [KJCX2-YW-H01]
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A novel polythreaded coordination network having both polyrotaxane and polypseudorotaxane characters was synthesized by using a flexible redox-active viologen derivative. Interestingly, a sandwich-type donor-acceptor-donor stacking is formed within each ring as a consequence of both types of polythreading in this species, and photoinduced and thermal-induced reduction of bipyridinium occurs with a color change from yellow to blue.
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