Journal
INORGANIC CHEMISTRY
Volume 47, Issue 3, Pages 772-774Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic701828w
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The hydrothermal reaction of (L)-ethyl lactate (Lig-Et) with Tb(CIO4)(3)center dot 6H(2)O gives colorless block (Lig)(2)Tb(H2O)(2)(CIO4) (1), in which 1 displays a laminar 2D framework. Ferroelectric and magnetic property measurements reveal that 1 probably is the first example of two ferroic metal-organic frameworks. Ferro-electricity of its analogue, (Lig)(2)Tb(D2O)(2)(CIO4) (2), further confirms the presence of the ferroelectric deuterium effect.
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