4.7 Article

Biphasic hydrogenation over PVP stabilized Rh nanoparticles in hydroxyl functionalized ionic liquids

Journal

INORGANIC CHEMISTRY
Volume 47, Issue 17, Pages 7444-7446

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic8009145

Keywords

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Funding

  1. China Scholarship Council
  2. EPFL-PKU
  3. NSF of China [20425619]
  4. Program for Changjiang Scholars and Innovative Research Teams in Universities [IRT 0641]

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Polyvinyl pyrrolidone stabilized rhodium nanoparticles are highly soluble in hydroxyl-functionalized ionic liquids, providing an effective and highly stable catalytic system. In hydrogenation reactions, excellent results were obtained, and transmission electron microscopy, solubility determinations, and leaching experiments were employed to quantify the advantages of this catalytic system.

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