Journal
INORGANIC CHEMISTRY
Volume 47, Issue 19, Pages 8562-8570Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic800696u
Keywords
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Categories
Funding
- Joint Project of Chemical Synthesis Core Research Institutions
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- [19GS0207]
- [18350097]
- [17105002]
- [19014010]
- [19340098]
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Recent findings on intriguing physical properties of new A-site-ordered perovskite structure oxides are reviewed. High-pressure and high-temperature conditions stabilize the square-coordinated Jahn-Teller Cu2+ ions in the original 12-fold-coordinated positions of the perovskite structure. The special-ordered arrangement of the square-coordinated A'O-4 units that align perpendicularly to each other sets a characteristic structural framework, and the presence of Cu2+ ions at the A' site and A'-B interactions play crucial roles for the diverse and intriguing physical properties.
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