Journal
INORGANIC CHEMISTRY
Volume 47, Issue 18, Pages 7942-7944Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic8007427
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Funding
- SEIC Board from the State of Michigan [454]
- University of Michigan's Electron Microbeam Analysis Laboratory for assistance with SEM equipment [EAR-9628196]
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The designed synthesis of heterobimetallic microporous coordination polymers (MCPs) is reported by a strategy employing the selective replacement of a single metal in homometallic MCPs with two unique metal coordination environments: octahedral and tetrahedral. This strategy is successful in the preparation of six mixed-metal MCPs, where Co/Zn and Ni/Zn versions of MOF-4 MOF-39, and a Zn-BTEC MCP are reported.
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