Journal
INORGANIC CHEMISTRY
Volume 47, Issue 15, Pages 7025-7028Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic801011g
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The preparation of Se(CN)(4) was attempted by the reaction of SeF4 with Me3SiCN at low temperatures. However, selenium tetracyanide could not be detected by NMR spectroscopy; instead, the decomposition product Se(CN)(2) was isolated and its crystal structure was redetermined. In the structure of Se(CN)(2), layers are present with secondary Se center dot center dot center dot N interactions. The structure of Se(CN)(4) and its reductive decomposition reaction has been calculated at the MP2 level of theory.
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