4.7 Article

Photoluminescent Mn4 Single-Molecule Magnet

Journal

INORGANIC CHEMISTRY
Volume 47, Issue 23, Pages 10798-10800

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic801485k

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Funding

  1. National Science Foundation

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The synthesis of [Mn-4(anca)(4)(Hmdea)(2)(mdea)(2)]center dot 2CHCl(3) (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.

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