Journal
INORGANIC CHEMISTRY
Volume 47, Issue 18, Pages 7957-7959Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic801049e
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Funding
- Major State Basic Research Development Program [2006CB806104, 2007CB925100]
- National Natural Science Foundation of China [20725104, 20531040]
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Two homochiral trinuclear clusters, {(MeTP)(2)Fe-2(CN)(6)Ni[(1R,2R)-chxn](2)} (1) and {(MeTp)(2)Fe-2(CN)(6)Ni[(1,3,2S)-chxn](2)} (2) [chxn = 1,2-diaminocyclohexane; MeTp = methyltris(pyrazolyl)borate), have been synthesized and structurally characterized. Ferroelectric and magnetic measurements reveal that they are rare examples of metal-organic compounds bearing ferroelectricity and intramolecular ferromagnetic interactions.
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