Journal
MEASUREMENT
Volume 69, Issue -, Pages 195-201Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.measurement.2015.03.025
Keywords
Inhibitor; Schiff base; Corrosion; Potentiodynamic polarization; Langmuir adsorption isotherm; Electrochemical impedance; Quantum chemical study
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Two novel Schiff bases derived from heterocyclic amines and aldehydes were synthesized and evaluated as corrosion inhibitors for mild steel in 1MH(2)SO(4) by mass loss and electrochemical techniques. Inorder to understand the mechanism of inhibition, adsorption isotherms were tested. The studies showed that the inhibition efficiency depends on concentration of inhibitor and temperature of measurements. Electrochemical studies showed that the inhibitors behave as mixed type. Quantum chemical studies were used to substantiate the experimental results. (C) 2015 Elsevier Ltd. All rights reserved.
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