Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 53, Issue 10, Pages 3898-3907Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie403768f
Keywords
-
Categories
Funding
- Fundamental Research Funds for the Central Universities of China [2011JDGZ15]
- Science and Technology Support Program of Jiangsu Province [SBE201038213]
- Applied Basic Research Program of Suzhou [SYN201004]
Ask authors/readers for more resources
Low service life limits the industrial application of the titanium-based Sb-SnO2 anode. To improve its stability, a titanium hydride interlayer is fabricated to construct a three-layer anode, Ti/TiHx/Sb-SnO2. Titanium hydride was prepared by reducing precoated titanium oxide in aqueous solution via electrochemical process, and it acted as a binder between the Ti and Sb-SnO2 phases. Cyclic voltammetry, electrochemical impedance spectroscopy, and the accelerated lifetime test were also conducted to elucidate the positive effect of the TiHx interlayer. Results show that Ti/TiHx/Sb-SnO2 not only possesses better stability but has higher oxygen evolution potential and lower electron transfer resistance compared with Ti/Sb-SnO2. Essential characterizations were conducted including scanning electron microscopy, energy disperse spectroscopy, and X-ray diffraction. The mechanism of lifetime enhancement is also proposed. The performances of the electrodes on degrading three different organics manifest that the degradation performance of the electrode strongly relies on the electrode stability.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available