Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 53, Issue 22, Pages 9120-9127Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie403549v
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- ETH Zurich (ETHIIRA proposal ) [ETH-33 11-1]
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Phosphine metal organic frameworks (P-MOFs) are an emerging class of coordination polymers that provide novel opportunities for metal supported catalysis as solid ligands. Here, we present the synthesis and characterization of three novel P-MOFs based on a (diphenylphosphino)terephthalic acid linker. We targeted the structures of MOF-5, MIL-101(Cr), and MIL-101(Al)-NH2 to produce materials with partial diphenylphosphine substitution, which were crystalline and highly porous.
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