Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 52, Issue 33, Pages 11510-11515Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie400909u
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Funding
- National Basic Research Program of China [2013CB933100]
- National Natural Science Foundation of China [20973166]
- BP Chemicals Limited
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Nanosized mordenites were found to show significantly enhanced reaction efficiency in dimethyl ether (DME) carbonylation to methyl acetate (MA) because of a greatly facilitated diffusion process. Copper incorporation into the channels of the nanosized mordenites further promoted the reaction rate, selectivity, and stability. Moreover, upon the addition of a small amount of H-2 (5-19 vol %) to the feed gas, deactivation was suppressed during DME carbonylation, whereas the catalyst stability and rate of formation of MA increased.
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