4.6 Article

Synthesis and Characterization of Thiazolium-Based Room Temperature Ionic Liquids for Gas Separations

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 51, Issue 35, Pages 11530-11537

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie3015632

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Funding

  1. U.S. Department of Energy, Advanced Research Projects Agency ENERGY
  2. U.S. Department of Energy
  3. Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy

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A series of novel thiazolium-bis(triflamide) based ionic liquids has been synthesized and characterized. Physicochemical properties of the ionic liquids such as thermal stability, phase transitions, and infrared spectra were analyzed and compared to the imidazolium-based congeners. Several unique classes of ancillary substitutions are examined with respect to impacts on overall structure, in addition to their carbon dioxide absorption properties in supported ionic-liquid membranes for gas separation.

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