4.6 Article

One-Pot Synthesis of 5-(Ethoxymethyl)furfural from Glucose Using Sn-BEA and Amberlyst Catalysts

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 51, Issue 14, Pages 5364-5366

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie2025536

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Funding

  1. Catalysis Center for Energy Innovation, an Energy Frontier Research Center
  2. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001004]
  3. NSF via MRSEC

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5-(Ethoxymethyl)furfural (EMF) was produced from glucose in ethanol in a single reactor at 90 C. The reaction proceeds via the isomerization of glucose to fructose with zeolite Sn-Beta, a Lewis acid catalyst. Fructose is converted to 5(hydroxymethyl)furfural, which is then etherified to EMF using a Bronsted acid catalyst, Arnberlyst 131. An EMF yield of 31% was achieved.

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