Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 51, Issue 19, Pages 6895-6906Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie3004336
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Funding
- Natural Science and Engineering Research Council of Canada (NSERC)
- Fonds Quebecois de Recherche sur la Nature et les Technologies (FQRNT)
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Flexible crystalline metal-organic framework (MOF) of nanosize particles (Al-MIL-53) and 6FDA-ODA polyimides were used to produce mixed matrix membranes (MMM). These MMM display excellent CO2/CH4 separation properties even without any compatibilization (amine grafting). The ideal selectivity and separation factor were found to increase with increasing MOF loading. Furthermore, these materials have an improved CO2/CH4 separation factor with increasing pressure, in contrast to traditional polymer membranes.
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