4.6 Article

Recoverable Platinum Nanocatalysts Immobilized on Magnetic Spherical Polyelectrolyte Brushes

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 51, Issue 15, Pages 5608-5614

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie2025147

Keywords

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Funding

  1. National Natural Science Foundation of China [20774028]
  2. Fundamental Research Funds for the Central Universities
  3. Shanghai Science and Technology Commission [10JC1403800, 10111100103]
  4. Chinese Scholarship Council

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Recoverable platinum nanocatalysts immobilized on magnetic spherical polyelectrolyte brushes (MSPB) were synthesized and characterized by high resolution transmission electron microscope (HRTEM), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). High catalytic activity was found by photometrically monitoring the reduction of 4-nitrophenol by NaBH4 in the presence of MSPB-Pt composites. An excellent stability and recyclability of catalyst was observed after consecutive eight runs following by external magnetic-separation and redispersion. This novel approach provides an excited potential application in preparation of recyclable metal nanocatalysts with high activity.

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