Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 50, Issue 14, Pages 8407-8419Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie101661m
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- UGC, Regional office, Bhopal, M. P., India
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Pd(II) catalyzed oxidation of paracetamol (PA) by sodium N-chloro p-toluenesulfonamide (chloramine-T or CAT) was studied in HClO4 and NaOH solutions at 303 K. The stoichiometry and the oxidation product in both solutions were found to be the same. The determined stoichiometric ratio was 1:2 ([PA]: [CAT]) and quinone oxime was identified as the oxidized product of PA. However, the kinetics patterns in both media were different. In the acidic medium, the rate law was -d[CAT]/dt = k[CAT][PA](0.9)[Pd(II)](0.8)[H+](-0.4) and the rate law was -d[CAT]/dt = k[CAT][PA](0.9)[Pd(II)] [PTS](-0.4)[NaOH](-1) in the alkaline medium. p-Toluenesulphonamide (PTS) is the reduced product of CAT. The kinetics of the reaction was studied as a function of temperature, ionic strength, concentration of the salt, concentration of the added reaction product, and dielectric constant of the medium to learn the mechanistic aspects of the reaction. A plausible mechanism is proposed, which is consistent with the kinetics, stoichiometry, and product of the reaction.
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