Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 47, Issue 9, Pages 2948-2955Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie071353a
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In the work reported in this article, 1-pentene reactions were carried out over USHY zeolite, whose strong-acid sites were selectively poisoned by hard coke to study the role of these strong zeolitic acid sites on hydrocarbon conversions. We show conclusively that strong-acid sites are responsible for cracking and hydride transfer reactions as well as strong coke formation, whereas weak-acid sites can only catalyze double-bond isomerization.
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