Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 47, Issue 16, Pages 5913-5917Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie8003732
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Funding
- Development and Research of China [2006BAC02A08]
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Various zinc compounds were used as the catalysts for the synthesis of dimethyl carbonate (DMC) from methyl carbarnate (MC) and methanol in a batch reactor. Among them, ZnCl(2) showed the highest catalytic activity and led to the DMC yield of 33.6% under the optimal conditions. In addition, a possible reaction mechanism was proposed based on Fourier transform infrared (FTIR) and X-ray diffraction (XRD) characterization results.
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