Journal
MATERIALS LETTERS
Volume 145, Issue -, Pages 104-107Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2015.01.086
Keywords
Composite materials; Microstructure; Lithium ion batteries; Electrical properties; Energy storage and conversion
Funding
- Science and Technology Program of Jilin Province [201105007]
- Jilin Province Science and Technology Development Program [201205009]
- Jilin Province Natural Science Foundation of China [201215026]
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Novel hierarchical porous SnO2/Mn2O3 core-shell microspheres (SMCM) are successfully prepared by wet chemistry method to grow SnO2 shell on the pre-obtained Mn2O3 microsphere core. As a result, these SnO2/Mn2O3 core-shell microspheres exhibit superior electrochemical performances as the advanced anode materials. Especially, the porous SnO2/Mn2O3 core-shell microspheres could exhibit high initial discharge capacity of 1365 mA h g(-1) and maintain a reversible capacity of 486 mA h g(-1) even after 400 cycles at 200 mA g(-1). The unique structural features of the porous, quasi-hollow structure comprised of interconnected nano-sized particles and the peculiar synergistic effect of SnO2/Mn2O3 are probably responsible for the enhanced performance. (C) 2015 Elsevier B.V. All rights reserved.
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