4.6 Article

A nickel-based metal-organic framework: A novel optimized anode material for Li-ion batteries

Journal

MATERIALS LETTERS
Volume 161, Issue -, Pages 712-715

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2015.09.079

Keywords

Metal-organic frameworks; Crystal structure; Energy storage and conversion; Lithium-ion batteries

Funding

  1. Fundamental Research Funds for the Central Universities [XDJK2014C051, SWU 113079]
  2. Municipal Natural Science Foundation of Chongqing [cstc2015jcyjA50031]

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A Ni-based metal-organic framework (MOF) was synthesized by a one-pot hydrothermal route and used as an anode material for lithium ion batteries (LIBs) for the first time. This Ni-based MOF has obvious ion diffusion channels which can be easily observed from its structural graph. As an anode material for LIBs, it delivers a reversible capacity of 620 mA h g(-1) at a current density of 100 mA g(-1) after 100 cycles. More importantly, it also shows excellent rate performance. Thus, this novel Ni-based MOF electrode will be a promising anode electrode for LIBs and further broaden the application field of MOFs materials. (C) 2015 Elsevier B.V. All rights reserved.

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