4.4 Article Proceedings Paper

Magnetic Investigation of CoFe2O4 Nanoparticles Supported in Biocompatible Polymeric Microsphere

Journal

IEEE TRANSACTIONS ON MAGNETICS
Volume 45, Issue 10, Pages 4059-4062

Publisher

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/TMAG.2009.2026291

Keywords

Magnetic coercive field; magnetization isotherm; polymer dispersed CoFe2O4 nanoparticles; thermal blocking process; magnetic fluid

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Magnetic investigation of spinel ferrite nanoparticles dispersed in biocompatible polymeric microspheres is reported in this study. X-ray diffraction data analysis confirms the presence of nanosized CoFe2O4 particles (mean size of similar to 8 nm). This finding is corroborated by transmission electron microscopy micrographs. Magnetization isotherms suggest a spin disorder likely occurring at the nanoparticle's surface. The saturation magnetization value is used to estimate particle concentration of 1.6 x 10(18) cm(-3) dispersed in the polymeric template. A T-1/2 dependence of the coercive field is determined in the low-temperature region (T < 30 K). The model of non-interacting mono-domains is used to estimate an effective magnetic anisotropy of K-eff = 0.6 x 10(5) J/m(3). The K-eff value we found is lower than the value reported for spherically-shaped CoFe2O4 nanoparticles, though consistent with the low coercive field observed in the investigated sample.

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