Journal
MATERIALS & DESIGN
Volume 66, Issue -, Pages 103-109Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2014.10.041
Keywords
Wood plastic composite; Graphitic carbon nitride; Mechanical properties; Thermal properties; Outward color
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Funding
- National Natural Science Foundation of China [21271087, 51172099, 11272093, 21006038]
- Foundation of Science and Technology Projects of Guangdong Province [2011B010700080]
- Jinan University Challenge Cup for Student Extracurricular Academic Science and Technology Work Competition [201312B07, 201312B49]
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The aim of this study was to evaluate and characterize various properties of experimental composition prepared from graphitic carbon nitride (g-C3N4), wood flour (WF) and polypropylene (PP). g-C3N4 with different concentrations (1 wt.%, 3 wt.%, 5 wt.% and 10 wt.%) were used as reinforcing filler for wood plastic compositions (WPCs). Maleic anhydride grafted polypropylene (PP-g-MA) was added as a coupling agent to increase the interaction between the components. Water absorption, morphology, physical, mechanical and thermal properties of the as-prepared composites were evaluated. The results showed that the tensile modulus of the composite was increased by 142.9% with increasing of g-C3N4 contents to 5 wt.%, reaching approximately 498 MPa compared to WPC. Moreover, the flexural and tensile strengths reached their maximum values when the concentrations of g-C3N4 were 1 wt.% and 3 wt.%, respectively. When maintaining the g-C3N4 at a low concentration, it was well dispersed in the WPC with thin plate shape. However, when more g-C3N4 (3-10 wt.%) was introduced, the enhancing effect began to diminish because of the agglomeration of g-C3N4 which caused poor interfacial adhesion. The water absorption results showed a lower value with the addition of 1 wt.% g-C3N4, and the thermal tests showed that the degradation temperature shifted to higher value clearly after the addition of g-C3N4. Besides, with the addition of g-C3N4 improved the outward color compared to the control sample. Crown Copyright (C) 2014 Published by Elsevier Ltd. All rights reserved.
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