Influence of anthropogenic activities on PAHs in sediments in a significant gulf of low-latitude developing regions, the Beibu Gulf, South China Sea: Distribution, sources, inventory and probability risk

Fifteen polycyclic aromatic hydrocarbons (PAHs) in 41 surface sediment samples and a sediment core (50 cm) from the Beibu Gulf, a significant low-latitude developing gulf, were analyzed. PAHs concentrations were 3.01-388 ng g(-1) (mean 95.5 ng g(-1)) in the surface sediments and 10.5-87.1 ng g(-1) (average 41.1 ng g(-1)) in the sediment core. Source apportionment indicated that PAHs were generated from coke production and vehicular emissions (39.4%), coal and biomass combustion (35.8%), and petrogenic sources (24.8%). PM-Is were mainly concentrated in the industrialized and urbanized regions and the harbor, and were transported by atmospheric deposition to the marine matrix. The mass inventory (1.57-2.62 t) and probability risk showed sediments here served as an important reservoir but low PAH risk. Different from oil and natural gas in developed regions, coal combustion has always been a significant energy consumption pattern in this developing region for the past 30 years (56 +/- 5%). (C) 2014 Elsevier Ltd. All rights reserved.