Fluoronitrile/CO2 Mixture as an Eco-Friendly Alternative to SF6 for Medium Voltage Switchgears

Recent studies suggest that fluoronitriles compound Novec (TM) 4710 possesses a dielectric strength two times higher than that of SF6, while with a low global warming potential of only 2400. Mixed with CO2 buffer gas, the Novec (TM) 4710 mixtures offer excellent dielectric properties and the possibility to be used as an eco-friendly alternative to SF6 for medium voltage switchgears. This paper focuses on the comparative study of the breakdown strength and partial discharge (PD) characteristics between the fluoronitrile/CO2 mixtures and SF6 under AC voltages. Breakdown tests are conducted under different electrode configurations, i.e., plane-plane, sphere-plane, rod-plane, and needle-plane, at different pressures and electrode gaps. In the uniform field, equivalent dielectric strength to SF6 at 100 kPa can be reached by a mixture containing 15% fluoronitrile at identical total pressure; while in non-uniform and highly non-uniform fields, SF6 exhibits higher dielectric strength than 20% mixture. The PD analysis suggests that SF6 has much more PDs with lower magnitude and the 20% fluoronitrile/CO2 mixture has less PDs but with higher magnitude. Due to the different PD characteristics, the corona stabilization effect may be responsible for the higher breakdown strength of SF6 under highly non-uniform field.