Journal
MACROMOLECULES
Volume 48, Issue 11, Pages 3414-3421Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.5b00463
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Funding
- National Natural Science Foundation of China [51273187, 21374107, 21474097]
- Fundamental Research Funds for the Central Universities [WK2060200012]
- Program for New Century Excellent Talents in Universities [NCET-11-0882]
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Multicomponent reactions have recently attracted a great deal of attention as they are considered as a powerful tool for constructing sequence-controlled polymers. Although new examples are constantly flourishing in the literature, the process that allows two or more consecutive multicomponent-reactions to react in a single operation for the syntheses of sequence-controlled polymers has not been developed until now. Here, we propose a new strategy combining multicomponent reaction of amine, thiol, and alkene conjugating and multicomponent polymerization of diyne, azide, and diamine coupling in one-pot for the synthesis of sequence-controlled polymer.
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