Journal
MACROMOLECULES
Volume 48, Issue 11, Pages 3431-3437Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.5b00555
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Funding
- National Natural Science Foundation of China [51373046, 51473045]
- Natural Science Foundation of Hebei Province [B2014202013]
- High-level Excellent Talents in University of Hebei Province
- Changjiang Scholars and Innovative Research Team in University [IRT13060]
- New Century Excellent Talents in University [NCET-10-0125]
- Fusion Research Program for Green Technologies through the National Research Foundation of Korea [2012M3C1A1054502]
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A facile strategy has been demonstrated for the selective synthesis of highly stereoregular polyesters with cis-2,3-(exo, exo) or trans-2,3-(exo, endo) repeating units by the organocatalysts mediated alternating copolymerization of cyclohexene oxide and norbornene anhydride (NA) stereoisomers. The geometrical structure of polyester can be tuned simply by modulating the type of NA isomers (endo- or exo-NA), monomer feed ratio, and reaction temperature. The cis- (>99%) and trans-polyesters (>99%) exhibit high glass transition temperature up to 129.8 and 115.9 degrees C, respectively. The resulting polyesters provide a versatile platform to incorporate various functional groups through the robust thiol-ene reaction of the pendant norbornenyl groups.
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