Journal
MACROMOLECULES
Volume 48, Issue 13, Pages 4301-4311Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.5b00946
Keywords
-
Categories
Funding
- National Energy Technology Laboratory (NETL)/Department of Energy (DOE) [RES1000026]
Ask authors/readers for more resources
Poly(dichlorophosphazene) is a versatile precursor material for accessing new polymeric materials via the introduction of various side groups by chlorine replacement reactions. Herein, methods are described for the synthesis of a new series of phosphazene single- and mixed-substituent high polymers containing cyclic aliphatic rings, -CnH2n-1, (where n = 4-8). These reactions were preceded by model reactions using small molecule cyclic trimeric phosphazenes. The new high polymers are amorphous, transparent, and film- and membrane-forming materials with a wide range of glass transition temperatures (-60 to +40 degrees C) depending on the side groups and cosubstituents. All are hydrophobic and resistant to hydrolytic breakdown.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available