Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 36, Issue 16, Pages 1492-1497Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201500167
Keywords
gold nanoparticles; host-guest interaction; pillararene; supramolecular chemistry; thermoresponsive polymers
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Funding
- National Natural Science Foundation of China [21204022]
- Research Fund for the Doctoral Program of Higher Education of China [20120076120005]
- Fundamental Research Funds for the Central Universities
- Large Instruments Open Foundation of East China Normal University [2014-15]
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Pillararene-containing thermoresponsive polymers are synthesized via reversible addition-fragmentation chain transfer polymerization using pillararene derivatives as the effective chain transfer agents for the first time. These polymers can self-assemble into micelles and form vesicles after guest molecules are added. Furthermore, such functional polymers can be further applied to prepare hybrid gold nanoparticles, which integrate the thermoresponsivity of polymers and molecular recognition of pillararenes.
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