Journal
MACROMOLECULAR MATERIALS AND ENGINEERING
Volume 300, Issue 11, Pages 1116-1122Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201500123
Keywords
click reaction; melamine; microporous material; post modification; Schiff base chemistry
Ask authors/readers for more resources
Although, current preparation methods for microporous organic polymers (MOP) based on coupling or condensations reactions are simple and flexible, they suffer from the requirement of additional modification steps for introducing properties for specific purposes. In the present work, we have developed a simple and rapid synthetic strategy to prepare MOP possessing reactive sites to incorporate any molecules of interest by Click Chemistry. The clickable MOP with high surface area was readily synthesized through Schiff base chemistry using propargylated anthraquinone and melamine in the catalyst free, one-pot process. The versatility of the click coupling on the acetylene functional MOP was demonstrated on a model reaction using independently prepared fluorescent azido-pyrene.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available