Recovery of nickel and cobalt from laterite leach solutions using direct solvent extraction Part 2: Semi- and fully-continuous tests

In Part 1 of this paper, two synergistic solvent extraction systems consisting of Versatic 10/LIX63/TBP and Versatic 10/4PC were assessed in batch tests for the separation and purification of nickel and cobalt from synthetic laterite leach solution after iron removal. In Part 2, semi- and fully-continuous tests are reported for the Versatic 10/LIX63/TBP system, with conditions optimised for separating nickel and cobalt from manganese, magnesium and calcium. Semi-continuous extraction tests were conducted using the synergistic organic system consisting of 0.50 M Versatic 10, 0.45 M LIX63 and 1.0 M TBP in Shellsol D70. With a pH profile of 5.5/6.1/6.5 for the three stages EX1/EX2/EX3 at 40 degrees C, the nickel and cobalt extractions were 99.9% with only 5 mg/L nickel and <1 mg/L cobalt left in the raffinate. With two stages of scrubbing and a pH profile of 5.4/5.0 at 40 degrees C, about 2 mg/L manganese and less than 1 mg/L magnesium and calcium were left in the scrubbed organic solution. With two stripping stages and an O/A ratio of 10 at 40 degrees C using 50 g/L H2SO4 as strip solution, the stripping efficiencies of nickel and cobalt were over 95%. A fully-continuous pilot plant was operated for 280 h. With an O/A ratio of about 2 and a pH profile of 5.5/ 5.8/6.0/6.3 for the four stages EX1/EX2/EX3/EX4 at 40 degrees C, both nickel and cobalt were almost completely extracted. The nickel and cobalt concentration in the raffinate was lower than detection limit of 0.2 mg/L The manganese, magnesium and calcium concentrations in the loaded organic solution were 34, 8 and 1 mg/L, respectively. Using a pH profile of 5.4/5.0 for SC1/SC2 at an O/A ratio of 10 and 40 degrees C, the manganese scrubbing efficiency was over 96% and the concentrations of manganese and magnesium in the scrubbed organic solution were <5 mg/L and that of calcium 1 mg/L Using three strip stages and a strip solution containing 50 g/L H2SO4 and 55 g/L Ni at an O/A ratio of 10 and 40 degrees C, over 98% Ni and 99% Co were stripped with only 64 mg/L Ni in the stripped organic solution. The nickel concentration in the loaded strip liquor was 86 g/L, giving a Delta Ni of 31 g/L. The loaded strip liquor contained less than 1 g/L acid. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.