Journal
LASER & PHOTONICS REVIEWS
Volume 9, Issue 6, Pages 706-712Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/lpor.201500170
Keywords
Degree of conversion; Raman microscopy; direct laser writing lithography; gradient-index lenses; polymers; interferometry
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Funding
- Lithuanian-French Programme Gilibert from the Research Council of Lithuania [TAP LZ-4/2015]
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We report a study of the determination of polymer cross-linking, namely the degree of conversion and refractive index of the microstructures created by two-photon polymerization (TPP). The influence of TPP processing parameters such as laser intensity and scanning velocity is investigated. The degree of conversion is analyzed via Raman microspectroscopy and the refractive index is measured with the interferometric technique employing a Michelson interferometer. Moreover, the relationship between these two properties is revealed and details are discussed. The largest refractive index change that we have obtained is of the order of 10(-2). Finally, we propose and demonstrate experimentally the realization of the gradientindex (GRIN) structure, resulting from a laser-induced local refractive index modification due to monomer cross-linking, i.e. degree of conversion. This work implies that the TPP technique is a valuable tool for the fabrication of GRIN microoptics for (in)homogeneous molding of light flow at the micrometer scale.
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