4.6 Article

Design of Nanohybrid Systems from a Partially Fluorinated Organogelator and Syndiotactic Polystyrene Thermoreversible Gel

Journal

LANGMUIR
Volume 31, Issue 27, Pages 7666-7672

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.5b01339

Keywords

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Funding

  1. French National Agency (ANR, project MATISSE) [11-BS08-001]
  2. joint venture of the French government and the Higher Education Commission (HEC) of Pakistan [2-2(7) PDFP-France/HEC/2012/01]
  3. CNRS [370478]

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Nanohybrid systems are prepared from organogels of a partially fluorinated molecule and from thermoreversible gels of syndiotactic polystyrene. The thermodynamic behavior, morphology, and Structure are investigated by using differential scanning calorimetry, atomic forte microscopy, small-angle X-ray scattering (SAXS), and small-angle neutron scattering (SANS). The outcomes of these investigations suggest that the fibrils of the organogel coil around the sPS fibril, probably through a heterogeneous nucleation process. These systems therefore differ from previously investigated sPS/OPV Systems (oligo vinylene phenylene) where OPV fibrils pervade the sPS network.

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