Journal
LANGMUIR
Volume 31, Issue 15, Pages 4552-4557Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.5b00277
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Funding
- DFG [IO 68/1-1, IO 68/1-3]
- Alexander von Humboldt Foundation
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This paper reports a novel approach for the design of self-folding films using reversibly cross-linkable thermoresponsive polymers with coumarin groups: poly(N-isopropylacrylamide-co-7-(2-methacryloyloxyethoxy)-4-methylcoumarin). We demonstrated that, depending on the structure of the films and the conditions of cross-linking/de-cross-linking, one can fabricate a variety of different forms ranging from simple tubes to complex centipede-like structures. The demonstrated approach opens new perspectives for the design of 3D self-assembling materials.
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