Journal
HIGH ENERGY CHEMISTRY
Volume 42, Issue 4, Pages 287-289Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0018143908040085
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The lifetimes of the lowest excited state and the Raman spectra of Pt(bpy)(4-X-PhS)(2) complexes were measured. The results are consistent with the assumption about the formation of transient three-electron sulfur-sulfur bond in the excited state and show that this bonding can be employed for controlling the excited-state reactivity.
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