Journal
HETEROCYCLES
Volume 88, Issue 1, Pages 245-260Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-13-S(S)11
Keywords
Hypervalent Compound; Iodine; Oxidative Cyclization; Spiro Compound; Lactam
Categories
Funding
- JSPS
- MEXT
- Ritsumeikan Global Innovation Research Organization (R-GIRO) project
- Asahi Glass Foundation
- NEDO of Japan
- Grants-in-Aid for Scientific Research [24689002] Funding Source: KAKEN
Ask authors/readers for more resources
In this report, the authors have clarified that the mu-oxo bridged heterocyclic hypervalent iodine compound 1 shows a more effective reactivity in the oxidative dearomatizing spirolactamization compared to conventional PIDA (phenyliodine(III) diacetate). Besides the high reactivity, a new selectivity during the oxidations based on the steric discrimination of the nitrogen groups of the pre-spirocyclic substrates is demonstrated for the heterocyclic hypervalent iodine compound 1.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
