Journal
HETEROCYCLES
Volume 85, Issue 8, Pages 1795-1819Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/REV-12-736
Keywords
Transition Metal Catalyst; C-B Bond Formation; B-H Compound; Organic Electrophile; Cross-Coupling Reaction
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Funding
- MEXT
- JSPS
- Grants-in-Aid for Scientific Research [23550113] Funding Source: KAKEN
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Metal-catalyzed cross-coupling reaction of B-H compounds provides a direct method for conversion of C-X bonds to C-B bonds. Dialkoxyboranes are excellent boron sources in the borylation of aryl, 1-alkenyl, allyl or benzyl halides or pseudohalides. These reactions tolerate large number of functional groups and proceeds with excellent yields, thereby allowing the simple, convenient, and elegant preparation of functionalized C-B compounds.
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