Journal
HETEROCYCLES
Volume 86, Issue 1, Pages 745-757Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-12-S(N)34
Keywords
Dual Activation; Asymmetric Reaction; Palladium; Enamine
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Funding
- KAKENHI [20229001, 23590038]
- Japan Prize Foundation
- Grants-in-Aid for Scientific Research [20229001, 23590038] Funding Source: KAKEN
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Direct asymmetric alpha-allylation of ketones with allylic alcohols is described. The combination of palladium with a new phosphine ligand bearing a chiral proline moiety promoted the reaction to afford the corresponding alpha-allylated ketones in moderate yield and enantioselectivity.
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